Ranking The Bulkiness Of Substituents On Cyclohexanes: A-Values
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The "steric influence" (or "bulk") of groups on a cyclohexane is quantified by measuring the equilibrium btw axial and equatorial. This is the "A-value"
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SOLVED: Table 2.3: AG and U-Values of Cyclohexane Derivatives Ep = Ar Ed = Gr + Gr' Ep = Ur Up' + % [Ar + Aq] R or R' A (kcal/mol) (kcal/mol)
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