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A rock slope can be characterized by tens of persistent discontinuities. A slope can be massive. The slip surface of the slope is usually easier to expand along with the discontinuities because the shear strength of the discontinuities is substantially lower than that of the rock blocks. Based on this idea, this paper takes a jointed rock slope in Hengqin Island, Zhuhai as an example, and establishes a three-dimensional (3D) model of the studied slope by digital close-range photogrammetry to rapidly interpret 222 fracture parameters. Meanwhile, a new Floyd algorithm for finding the shortest path is developed to realize the critical slip surface identification of the studied slope. Within the 3D fracture network model created using the Monte Carlo method, a sequence of cross-sections is placed. These cross-sections containing fractures are used to search for the shortest paths between the designated shear entrances and exits. For anyone combination of entry point and exit point, the shortest paths corresponding to different cross-sections are different and cluttered. For the sake of safety and convenience, these shortest paths are simplified as a circular arc that is regarded as a potential slip surface. The fracture frequency is used to determine the probability of sliding along a prospective critical slip surface. The potential slip surface through the entrance point (0, 80) and exit point (120, 0) is identified as the final critical slip surface of the slope due to the maximum fracture frequency.